Subject Area
Chemistry
Abstract
In this dissertation, we have investigated the complex interplay of atomic composition, structural modifications in covalent organic frameworks (COFs), and atomic-level designs in bimetallic chiral nanoclusters (NCs). By synthesizing COFs and bimetallic NCs, we elucidated how these elements govern their exceptional catalytic, optical, and electronic properties. Our work demonstrates that precise atomic adjustments, tailored pore engineering in COFs, and the strategic use of chiral ligands in NCs enable fine-tuned reactivity and stability. These advancements were applied to enhance photocatalytic performance, optimize iodine adsorption, and facilitate asymmetric A3 coupling reactions, laying a robust foundation for practical applications and future innovations in materials science.
Degree Date
Spring 4-28-2025
Document Type
Dissertation
Degree Name
Ph.D.
Department
Chemistry
Advisor
Anindita Das
Number of Pages
161
Format
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial 4.0 License
Recommended Citation
E Kenari, Melika, "From Clusters to Frameworks: Synthesis, Engineering, and Application of Sub-2-Nanometer Nanoclusters and Microporous Covalent Organic Frameworks" (2025). Chemistry Theses and Dissertations. 56.
https://scholar.smu.edu/hum_sci_chemistry_etds/56
